While the headspace composition predicted using vapor–liquid equilibrium theory was closely correlated to measurements, E85 vapor concentrations were underpredicted. B20 and ULSD were dominated by C 9 to C 16 n-alkanes and low levels of the aromatics, and the two fuels had similar headspace vapor composition and concentrations. Temperature changes produced greater changes in the partial pressures of 17 VOCs in E85 than in gasoline, and large shifts in the VOC composition. Despite its low gasoline content, E85 vapor contained higher concentrations of several VOCs than those in gasoline vapor, likely due to adjustments in its formulation. The composition of gasoline and E85 in both neat fuel and headspace vapor was dominated by aromatics and n-heptane. This study examines the liquid and vapor (headspace) composition of four contemporary and commercially available fuels: gasoline (<10% ethanol), E85 (85% ethanol and 15% gasoline), ultra-low sulfur diesel (ULSD), and B20 (20% soy-biodiesel and 80% ULSD). Information regarding the volatile organic compound (VOC) composition of motor fuels other than gasoline is scarce, especially for bioethanol and bio-diesel blends. The formulation of motor vehicle fuels can alter the magnitude and composition of evaporative and exhaust emissions occurring throughout the fuel cycle.
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